MAFS’ James Susler looks agitated as he puffs on a cigarette outside a Melbourne bar

Is everything okay? Married At First Sight’s James Susler looks agitated as he puffs on a cigarette outside a Melbourne bar

Married At First Sight‘s James Susler shocked his ‘wife’ Joanne Todd by confessing he is ‘in love with another woman’ on Sunday night.

But just one day before the episode aired, the luxury car salesman seemed to be on edge during a night out in Melbourne.

The 44-year-old looked agitated as he puffed on a cigarette and spoke to a mystery woman outside a bar.

Is everything okay? Married At First Sight groom James Susler (pictured) looked agitated as he puffed on a cigarette outside a Melbourne bar on Saturday

Stressed: James seemed to be on edge as he spoke to a mystery woman outside a bar

Stressed: James seemed to be on edge as he spoke to a mystery woman outside a bar

James wore a casual ensemble consisting of black jeans, a white T-shirt and a denim jacket.

The car salesman, who is known for his expensive taste, teamed the outfit with a pair of white Gucci sneakers and a belt.

After leaving a Melbourne bar, James looked agitated as he had a tense conversation with a female friend.

However, his ‘wife’ Joanne was nowhere to be seen.

Casual: He wore a casual ensemble consisting of black jeans, a white T-shirt and a denim jacket

Casual: He wore a casual ensemble consisting of black jeans, a white T-shirt and a denim jacket

On Sunday night, James made a surprising confession to Jo during the commitment ceremony.

He shocked her when he confessed his love for new sexologist Alessandra Rampolla.

But things took an awkward turn when Alessandra shut James, 44, down and labelled his behaviour as ‘disrespectful’.

Accessories: The car salesman, who is known for his expensive taste, teamed the outfit with a pair of white Gucci sneakers and a belt

Accessories: The car salesman, who is known for his expensive taste, teamed the outfit with a pair of white Gucci sneakers and a belt

Agitated: James looked stressed as he had a tense conversation with a female friend

Agitated: James looked stressed as he had a tense conversation with a female friend

During the commitment ceremony, James shocked his co-stars when he said: ‘I think I’m just going to come clean and say something to you.’

‘I can’t deny it anymore. I’m in love with another woman. Can I tell you who it is?’

A stunned Jo then asked James whether he had feelings for another woman in the experiment.

‘Yeah, it’s Alessandra,’ he confessed.

Is it over? However, his 'wife' Joanne Todd was nowhere to be seen

Is it over? However, his ‘wife’ Joanne Todd was nowhere to be seen

Confession: It comes after James shocked his 'wife' Joanne Todd by confessing he is 'in love with another woman' on Sunday night

Confession: It comes after James shocked his ‘wife’ Joanne Todd by confessing he is ‘in love with another woman’ on Sunday night

The unimpressed Puerto Rican sexologist, 46, responded: ‘I don’t get the joke. I think it’s incredibly disrespectful to Jo sitting next to you.’

‘I was only joking… I was trying to lighten up the mood. Sorry,’ James admitted.

Alessandra said: ‘It’s not a good joke.’

Married At First Sight continues Monday at 7.30pm on Channel Nine 

Shocking! During the commitment ceremony, James shocked his co-stars and wife Jo when he said: 'I think I'm just going to come clean and say something to you. I can't deny it anymore. I'm in love with another woman... it's Alessandra'

Shocking! During the commitment ceremony, James shocked his co-stars and wife Jo when he said: ‘I think I’m just going to come clean and say something to you. I can’t deny it anymore. I’m in love with another woman… it’s Alessandra’

James later admitted: 'I was only joking¿ I was trying to lighten up the mood. Sorry'

James later admitted: ‘I was only joking… I was trying to lighten up the mood. Sorry’